Yes, they broke up in Frost & Fire. Finn tried to get back to Princess Bubblegum in the following episode, Too Old, but he rejected him because she was focusing on some レモン child (I forgot his name). At the end of Too Old, Finn 発言しました he would try to fix things up with Flame. In Earth & Water, FP becomes Flame Queen. When Finn asked if they were still going out, she 発言しました no but they could still be good フレンズ if he was completely honest to her.
Not really, in that episode FP 発言しました she needed some time alone but in the following episodes she 発言しました they can still be フレンズ and she took over as her her father