As a captain of the Gotei 13, Byakuya is extremely skilled in all forms of Soul Reaper combat. In keeping with his rank, Byakuya's abilities allow him to defeat opponents of captain-level ability without much effort.
Of particular note is Byakuya's speed: he is skilled in the use of flash steps, having trained with (but never surpassed) Flash Master Yoruichi Shihōin. Yoruichi also taught Byakuya some techniques of her own creation that involved flash steps, including one called utsusemi (空蝉, lit. empty cicada, in reference to their molting), which allows Byakuya to 移動する out of harm's way...
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